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Project

Physical Chemistry Division (I)

COMMISSION ON THERMODYNAMICS
SUBCOMMITTEE ON THERMODYNAMIC DATA

Number: 121/16/93

Title: Vapour-Liquid-Equilibria and Related Properties in Binary and Ternary Mixtures of Ethers with l-Alkanols and n-Alkanes

Coordinator(s): J.H. Dymond

Completion Date: 1999

Progress:
The Second Workshop was held in Valladolid, Spain, July 3-5 1996 with 24 oral presentations and 26 posters. Twenty papers were selected for publication in a Special Issue of Fluid Phase Equilibria, Vol. 133 (1/2), 1- 270 (1997).

A very successful Third and Final workshop was held as part of the 15th. IUPAC International Conference on Chemical Thermodynamics, Porto, Portugal, August 1998, with 10 oral and 11 poster presentations and a final round-table discussion. Selected papers were published as : Special Issue, 3rd International Workshop on Vapour-liquid equilibria and related properties in binary and ternary mixtures of ethers, alkanes and alkanols, Fluid Phase Equilibria, Vol. 156, 1-236 (1999). The following key systems were identified as being of particular interest with a need for further experimental measurements of all the relevant properties:
MTBE + methanol + hexane/heptane
TAME + amyl alcohol + hexane/heptane
Diethyl ether + ethanol + pentane/hexane/heptane

Project completed.

Last update: 2 June 1999

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