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Macromol. Symp., Vol. 134, 1998, pp. 1 - 198

IUPAC Symposium on Electron Transfer Processes and Reactive Intermediates in Macromolecular and Organic Chemistry


Krakow, Poland 1997

Contents  
Preface
Z. Jedlinski
Carbenoids, nitrenoids, oxenoids: very electrophilic "anions" 1
G. Boche
Electron transfer at the solid liquid interface; new insights on the mechanism of formation of the Grignard reagent 13
M. Chanon*, J. C. Négrel, N. Bodineau, J. M. Mattalia, E. Péralez, A. Goursot
Alkali metals plus complexants: from alkalides and electrides to aromatic anions 29
J. L. Dye
Polymer catalysts for important photoelectron transfer reactions 41
J. E. Guillet, N. A. D. Burke, M. Nowakowska, S. Paone
Novel electron transfer polymerization processes with alkali metal supramolecular complex as catalyst 51
Z. Jedlinski
Mechanistic aspects of the olefin polymerization with metallocene catalysts 63
W. Kaminsky
Electron transfer in some nucleophilic reactions 73
H. Lund*, K. Daasbjerg, T. Lund, S. U. Pedersen
Scission of C-C o-bonds via electron transfer processes 83
A. Maercker*, V. E. E. Daub, A. Deskowski, K.-D. Klein, K. S. Oeffner H. Schutz

New adventures with divalent carbon intermediates

95
A. P. Marchand*, D. Rajagopal, K. A. Kumar, R. Eckrich, K. C. V. Ramanaiah, I. N. N. Namboothiri, S. Alihodzic, E. Z. Dong, R. Shukla, S. G. Bott*, G. Mloston, A. Galindo, R. Bartnik
Inner sphere and outer sphere electron transfer reactions in atom transfer radical polymerization 105
K. Matyjaszewski

Grafting and initiation reactions 119
B. Rånby
Electron photoejection and its application in studies of electron transfers 135
M. Szwarc
"Bonding" electropolymerization: a new electron-transfer strategy for the tailoring of performant polymer-based composite 157
N. Baute, C. Calberg, P. Dubois, C. Jérome, R. Jérome, L. Martinot, M. Mertens, P. Teyssié
Intra- and intermolecular reactions of nucleophilic carbenes 167
J. Warkentin
Initiation of cationic polymerization by photoinduced electron transfer 177
Y. Yagci
A chemical scale for evaluating the electron transfer ability of alkylcopper reagents 189
Y. Yamamoto*, Y. Chounan
* The asterisk indicates the name of the author to whom inquiries should be addressed.

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