Transition-metal-catalyzed reactions of carbon-heteroatom bond formation by substitution and addition processes*
I. P. Beletskaya
Chemistry Department, Moscow State University, Leninskie Gory, 119992, Moscow, Russia
Abstract: Two types of transition-metal-catalyzed cross-coupling reactions, which both lead to the formation of carbon-heteroatom bonds, are considered: RX + E-H and E-X + RM. The potential of addition reactions of E-H or E-E to double or triple bond in C-E bond formation is also demonstrated.
Keywords: Transition-metal-catalyzed reactions; homogeneous catalysts; carbon-carbon; carbon-heteroatom; bond formation; Ullmann reaction.
*Paper based on a presentation at the 7th IUPAC International Conference on Heteroatom Chemistry (ICHAC-7), Shanghai, China, 21-25 August 2004. Other presentations are published in this issue, pp. 1985-2132.