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Macromol. Symp., Vol. 182, 2002, pp. 1-303

3rd IUPAC-Sponsored
International Symposium on
Free-Radical Polymerization:
Kinetics and Mechanism


Macromolecular Division
June 3-9, 2001
Il Ciocco (Lucca), Tuscany, Italy

 

Contents

Preface, M. Buback, A.L. German

Fundamentals of Free-Radical Polymerization  

Factors Controlling the Addition of Carbon-Centered Radicals to Alkenes

1

Hanns Fischer*, Leo Radom

New Aspects of Chain-Length Dependent Termination

15

Oskar Friedrich Olaj*, Andreas Kornherr, Philipp Vana, Monika Zoder, Gerhard Zifferer

Propagation Kinetics in Free-Radical Polymerizations

31

Sabine Beuermann

Shining a Light on Catalytic Chain Transfer

43

Sebastiaan C. J. Pierik, Rainer Vollmerhaus, Alex M. van Herk*, Anton L. German

Penultimate Unit Effects in Free Radical Copolymerization

53

Takeshi Fukuda*, Atsushi Goto, Yungwan Kwak, Chiaki Yoshikawa, Yung-Dae Ma

Initiating Free Radical Polymerization

65

Graeme Moad*, John Chiefari, Roshan T A. Mayadunne, Catherine L. Moad, Almar Postma, Ezio Rizzardo, San H. Thang

The Photocopy Method: Measuring Living Chain Distributions in Radical Polymerization

81

Erdem Karatekin, Ben O'Shaughnessy*, Nicholas J. Turro

Initiation and Termination Kinetics in Fluid-Phase Free-Radical Polymerization up to High Pressure

103

Michael Buback

Continuous Precipitation Polymerization of Vinylidene Fluoride in Supercritical Carbon Dioxide: Molecular Weight Distribution

119

Manish K. Saraf, Louis M. Wojcinski II, Karen A. Kennedy, Sylvain Gerard, Paul A. Charpentier, Joseph M. DeSimone, George W Roberts*

 

Polymer Characterization

 

Transfer and Propagation Reactions in Free Radical Copolymerization

131

Thomas P. Davis*, Johan P.A. Heuts, Christopher Barner-Kowollik, Simon Harrisson, David A. Morrison, Lachlan H. Yee, Heidi M. Kapfenstein-Doak, Michelle L. Coote

Studies of Higher Temperature Polymerization of n-Butyl Methacrylate and n-Butyl Acrylate
149

Michael C. Grady*, William J. Simonsick, Robin A. Hutchinson

 

 

Polymer Reaction Technology

 

The Value of Fundamental Modeling in the Design and Operation of Controlled Free Radical Polymerization Processes

169

Min Zhang, W Harmon Ray*

Emulsion Polymerization: Radical Segregation and Its Role in Controlled Polymerization
181
Alessandro Butté, Giuseppe Storti, Massimo Morbidelli*  

A New Arithmetic for Linear Free Radical Copolymerization

195

Jon A. Debling, Fouad Teymour*

 

Controlled Radical Polymerization

 

Structure-Reactivity Correlation in Atom Transfer Radical Polymerization

209

Krzysztof Matyjaszewski

Design and Use of b-Phosphorus Nitroxides and Alkoxyamines in Controlled/"Living" Free Radical Polymerizations
225

Christophe Le Mercier, Sébastien Acerbis, Denis Bertin, Florence Chauvin, Didier Gigmes, Olivier Guerret, Muriel Lansalot, Sylvain Marque, François Le Moigne, Hanns Fischer, Paul Tordo* 

Nitroxide-Mediated Miniemulsion Polymerization of n-Butyl Acylate: Synthesis of Controlled Homopolymers and Gradient Copolymers with Styrene
249

Céline Farcet, Bernadette Charleux*, Rosangela Pirri 

Effect of Water on Copper Mediated Living Radical Polymerization
261
Sébastien Perrier, David M. Haddleton*

 

Polymerization in Heterogeneous Systems

 
Nitroxide-Mediated Living Radical Polymerization in Miniemulsion
273

M. F Cunningham*, K. Tortosa, J. W Ma, K. B. McAuley, B. Keoshkerian, M. K. Georges 

Emulsion Polymerization of Hydrophobic Monomers
283

Willie Lau

Control of Microstructural Properties in Emulsion Polymerization Systems
291

M. Vicente, J. R. Leiza, J. M. Asua *

 
 

* Corrresponding author


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