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Committee On Chemistry and Industry (COCI)

Reliability problem in chemical measurement

As part of its task to identify projects of interest to the chemical industry, COCI has decided to tackle the reliability problem in chemical measurement.

The wide variation in chemical trace measurements was first brought to COCI attention by Prof. DeBi�vre at the Committee meeting in 1998. During the 1999 meeting in Berlin, Prof. DeBi�vre presented data demonstrating a huge (+-50%) variation in trace element (Pb, Cd, Fe, and Zn) concentrations in water from even "accredited" laboratories. Similar problems were demonstrated for analysis of catalyst (Pt) metals in car exhaust material.

Although a brief summary of the concerns "Metrology in Chemistry", had been published in C&EN (May 31, 1999, p.29), COCI encouraged Prof. DeBi�vre to submit a summary to Chemistry International. The article provides "snapshot" pictures of chemical measurement (un)reliability, with many practical, societal implications. This is also part of COCI' s response to an IUPAC request for submission of articles of a topical/global nature.

> Read 'Quality of chemical measurements in water - International evaluation programme reveals true situation', authored by C. Nicholl, P.D.P. Taylor, I. Papadakis, and P. De Bi�vre, Chem. Int. 23(1), pp. 1-7, 2001


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